據(jù)氣體世界網(wǎng)2022年7月6日報道，英國知名研究公司IDTechEx最近披露的一項研究報告顯示，由于越來越多的行業(yè)開始利用碳捕獲技術(shù)，通過將捕獲的二氧化碳轉(zhuǎn)化為低碳、可降解的聚合物，這種技術(shù)可以幫助減少碳排放和塑料垃圾。

IDTechEx的這份題為《2022-2042：二氧化碳利用技術(shù)、市場預(yù)測和參與者》的報告探討了與二氧化碳聚合物技術(shù)相關(guān)的機(jī)遇和挑戰(zhàn)。

2019年，全球塑料產(chǎn)量達(dá)到4.6億噸，盡管近幾年來使用了更多基于回收的技術(shù)，但經(jīng)合組織的一項研究顯示，全球塑料消費(fèi)仍將會增加。

為了促進(jìn)循環(huán)碳經(jīng)濟(jì)，捕獲的碳可以利用電化學(xué)、生物轉(zhuǎn)化和熱催化來制造各種聚合物。 

熱催化被認(rèn)為是最成熟的二氧化碳利用技術(shù)，它可以直接產(chǎn)生生物可降解的線性鏈聚碳酸酯（LPCs），或者通過使用甲醇和乙醇等化學(xué)物質(zhì)進(jìn)行聚合反應(yīng)來間接利用。 

諸如聚氨酯（PUR）那樣的LPCs通常用于電子、地膜、泡沫和生物醫(yī)藥/保健等行業(yè)。聚氨酯的主要成分之一是多元醇，它可以組成高達(dá)50%（在重量上）的二氧化碳。 

為了制造這些多元醇，二氧化碳先與環(huán)醚（一種環(huán)狀分子，稱為環(huán)氧化合物，含氧）結(jié)合，然后再與異氰酸酯組成合成PUR。 

雖然不是完全無碳的，但在通過熱化學(xué)法制造塑料時，以化石為基礎(chǔ)的過程是由廢棄的二氧化碳來支持的，以節(jié)省原材料成本。  

電化學(xué)和微生物合成等不太成熟的技術(shù)還在開發(fā)中。 

微生物合成等生物過程被認(rèn)為比電化學(xué)過程更成熟，已經(jīng)達(dá)到早期的商業(yè)化階段，美國加州的Newlight公司已經(jīng)開發(fā)出一種利用特定微生物將捕獲的二氧化碳、空氣和甲烷轉(zhuǎn)化為可降解聚合物的方法。

根據(jù)這份報告，目前其他成功的商業(yè)操作包括日本旭化成公司從二氧化碳中生產(chǎn)芳香族聚碳酸酯的努力?？偛课挥诿绹睦蕽杉夹g(shù)公司還與聯(lián)合利華（Unilever）、歐萊雅（L’oreal）、安恩（On）和達(dá)能（Danone）等主要品牌合作，從工業(yè)過程中捕獲的碳排放中生產(chǎn)聚合物前驅(qū)體。

盡管這是一項明顯的“雙贏”技術(shù)，但人們?nèi)匀粨?dān)心它是否真的會導(dǎo)致大量碳排放，以及潛在的經(jīng)濟(jì)障礙，可能會減緩商業(yè)化。 

IDTechEx表示：“由于世界對塑料的渴求似乎沒有減弱，循環(huán)碳經(jīng)濟(jì)通過培育一個將廢棄的二氧化碳視為可行原料的石化行業(yè)可能有助于維持人們的生活方式。”

李峻 編譯自 氣體世界網(wǎng)

原文如下：

Turning CO2 into plastics

As more industries begin to utilise carbon capture, technologies could help reduce both emissions and plastic waste by turning captured CO2 into low-carbon, degradable polymers, according to a recent study by IDTechEx.

The report, titled ‘Carbon Dioxide (CO2) Utilisation 2022-2042: Technologies, Market Forecasts, and Players’ explored both opportunities and challenges associated with CO2-based polymer technology. 

In 2019, global plastic production rates hit 460m tonnes and - although more recycling-based technologies have been deployed in recent years - an OECD study revealed that plastic consumption is set to increase. 

To advance a circular carbon economy, captured carbon could be utilised to created various polymers with electrochemistry, biological conversion, and thermocatalysis. 

Considered more developed than electrochemical processes, biological processes such as microbial synthesis have reached the early-commercialisation stage, with companies such as California-based Newlight having developed a method to turn captured CO2, air, and methane into degradable polymer using a specific microbe. 

According to the report, other successful commercial operations currently include Asah Kasei’s efforts to make aromatic polycarbonates from CO2. 

US-based LanzaTech has also worked with major brands such as Unilever, L’Oreal, On, and Danone to make polymer precursors from carbon emissions captured from industrial processes. 

Despite it being an apparent ‘win-win’ technology, there are still concerns over whether it will actually lead to significant emissions, in addition to potential financial barriers that may slow down commercialisation. 

“As the world’s thirst for plastics does not seem to fade, a circular carbon economy may help maintain people’s lifestyles by fostering a petrochemical industry that sees waste CO2 as a viable feedstock,” stated IDTechEx.

Considered more developed than electrochemical processes, biological processes such as microbial synthesis have reached the early-commercialisation stage, with companies such as California-based Newlight having developed a method to turn captured CO2, air, and methane into degradable polymer using a specific microbe. 

According to the report, other successful commercial operations currently include Asah Kasei’s efforts to make aromatic polycarbonates from CO2. 

US-based LanzaTech has also worked with major brands such as Unilever, L’Oreal, On, and Danone to make polymer precursors from carbon emissions captured from industrial processes. 

Despite it being an apparent ‘win-win’ technology, there are still concerns over whether it will actually lead to significant emissions, in addition to potential financial barriers that may slow down commercialisation. 

“As the world’s thirst for plastics does not seem to fade, a circular carbon economy may help maintain people’s lifestyles by fostering a petrochemical industry that sees waste CO2 as a viable feedstock,” stated IDTechEx.